In addition to what has been said before about the PHP versions.
We regularly get messages here about Printful, there actually was one just yesterday. Most people try to use it with WooCommerce: WooCommerce Printful Webhook Blocked by mod_security
But the answer is always the same: it will not work due to free hosting restrictions. Printful needs to call webhooks on your site to work, but they are blocked by this security system:
So to be clear: this is a hosting restriction which appears to be fundamentally incompatible with Printful’s integration. It’s not a problem with your website software, so switching from WooCommerce to Prestashop, or downgrading to an older PrestaShop version will not fix it.